Isoelectric p H

Definition:
Isoelectric pH (pI) is the pH at which an amino acid or protein carries no net electrical charge - the positive and negative charges are equal.

Key point:
At pI, the molecule does not migrate in an electric field.

Examples (real data):

  • Glycine → pI = 6.0

  • Albumin → pI ≈ 4.7

  • Hemoglobin → pI ≈ 6.8

Formula (for simple amino acids):

pI=pKa of acidic group + pKa of basic group2

Short Answer:

It is the pH at which an amino acid or protein has no net charge and does not move in an electric field.
Example: Glycine has pI ≈ 6.0.